HomeMy WebLinkAbout07-7152
CITY OF ZEPHYRHILLS
5335 - 8TH STREET
(813) 780-0020
FUMIGATION TENT PERMIT
7152
Permit Number: 7152
Permit Type: FIRE FUMIGATION TENTING
Class of Work: FIRE-FUMIGATION TENT
Proposed Use: NOT APPLICABLE
Square Feet:
Est. Value:
Improv. Cost:
Date Issued:
Total Fees: 50.00
Amount Paid: 50.00
Date Paid: 10/30/2007
Work Desc: FUMIGANTION TENT INSTALLATION
Address: 5418 19TH ST
ZEPHYRHILLS, FL.
Township: Range: Book:
Lot(s): Block: Section:
Subdivision: CITY OF ZEPHYRHILLS
Parcel Number: 11-26-21-0010-14400-0080
Name: HARDY, JANET
Address: 5418 19TH ST
ZEPHYRHILLS, FL. 33542
Phone:
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Chapter 633, Florida Statutes, authorizes the City to charge and collect user fees to pay for the costs of fire
prevention and protection related activities such as inspections, plan review, administrative fees, and other
costs related to the aforementioned.
Complete Plans, Specifications and Fee Must Accompany Application. Commencement of work without written approval of
the Fire Department's Fire Marshal or required permits or opening up for commercial activity without an approved final
inspection shall be charged double permit fee per day of operation or a minimum of $100.00, whichever is greater. All
work shall be performed in accordance with City Codes and Ordinances.
-~ ~ ~
.I ~CTc;R SIGNATUR - - p - -I: O~I~ER
PERMIT EXPIRES IN 30 DAYS WITHOUT APPROVED INSPECTION
CALL FOR INSPECTION - 8 HOUR NOnCE REQUIRED
ZEPHYRHILLS FIRE RESCUE DEPT - Fire Marshal Office - 813-780-0041
~116v
Date Received
City of Zephyrhills Fire
Permit Application
Phone Contact for Permit
813-780-0020
Owner's Name
-0
:. l:1tlnA4 / JlJ'leI
Owner's Address
Fee Simple Titleholder Name
Fax-813-780-o021
Owner's Phone Number
II
II
I Titleholder Phone Number I
II
II
Fee Simple Titleholder Address
Ie; TII 5/
Job Address
I 54/<6
I
ZfiP HyP. }/II..LS
I Parcel #
Sub Division
o Bio-Hazard Waste Storage - ANNUAL
D Comm Exhaust Kitchen Hood/Duct
D Controlled Bum
D Emergency Generator < 30 kw
o Emergency Generator> 30 kw
o Fire Protection Maintenance - ANNUAL
Sprinkler D
Fire Alarm D
Hood Clean/Suppression D
Fire Alarm Installation
D
D
D
D
D
D
D
D
D
D
D
o
D
D
D
D
D
c~ntractor !
Signature .
Address
ELECTRICIAN
Signature I
Address I
PLUMBER I
Fire Pumps
Fire Works
Flammable Application- ANNUAL
Fuel Tanks
33SLfd-.
I
I Lot#
(!~::c: !!u7~~!u~;~f~u~~P
Fumigation Tent
Hazardous Material (Tier" or RQ Facility) ANNUAL
Hood Installation
LP/Natural Gas-Installation
LP/Natural Gas-ANNUAL Sale
Places of Assembly-ANNUAL
Recreational Bum
Sparklers
Sprinkler System Installations
Standpipes (Sprinkler Sys)
Torch Roofing
Waste Tire Storage ANNUAL
Valuation of Project
Other:
~
I~
Signature
Address I
MECHANICALI
Signature
Address I
OTHER
Signature
Company
Registered
BOLT/~ PEST C;:;"vrev<.-
Y I N I Fee Current I Y I N
I~
I
I
I
I
License #
Company
Registered
License #
Y I N I Fee Current
Y/N
Company
Registered
License #
Y I N I Fee Current
Y/N
Company
Registered
License #
Y I N I Fee Current
Y/N
Company
Registered
License #
Y I N I Fee Current
Y/N
Fill out application completely.
Owner & Contractor sign back of application, notarized (Or, copy of signed contract with owner)
If over $2500, a Notice of Commencement is required (Mechanical work over $5000)
Supply two (2) sets of drawings with applicable documentation
Allow 10-14 days for review after submittal date.
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Fax# 1-727-507-4155
BOLTIN PEST CONTROL, INC.
NOTICE OF FUMIGATION
LOCATION: 5418 19th Street, Zephyrhills, FL 33542
Type (House, Apt., Store):
Fwnigant (Brom-O- Gas, Vikane):
House
Zythor
*
Approx. Time: 3pm
10-31-07 (WEDS)
Scheduled: Date:
Exposure Period: 24 Hours
Certified Operator in Charge:
HERBERT BOLTlN,]R.
* 3pm is approximate time we will
shoot the gas. Our technicians
will be at the site at Bam to
put up the tent.
Dade City
352-567-2395
Toll Free
888-272-2871
15534 U.S. 301, Dade City, Florida 33523
Material Safety Data Sheet
CARDINAL PROFESSIONAL PRODUCTS
8770 HIGHWAY 25, HOLLISTER, CA 95023
OFFICE PHONE: (831) 637-1992
EMERGENCY PHONE NUMBERS: (800) 655-7262, CHEMTREC (800) 424-9300
Revision Date: 06/30/03
--'
SECTION I
PRODUCT NAME:
SYNONYMS:
CHEMICAL FORMULA:
CAS NUMBER:
CHLOROPICRIN CLEARING/WARNING AGENT
ohloroplorln, trlchloron/tromethane, nltroohloroform, n/trotrlchloromethano
CCI~N02 NFPA: Health.4, Flre-O, Reactlvlty.~
7~0~2 DO~ Inhalation Hazard 6, UN IS80
~
. II. HAZARDOUS INGREDIENTS/lDENTIlY INFORMATION
CHEMICAL NAME
chloropicrin
PERCENT
99.0
ACGIH TlV
0.1 ppm
OSHA PEL
0.1ppm
OWER
III. PHYSICAL/CHEMICAL CHARACTERISTICS
~
BOILING POINT: 2340 F (1120 C)
VAPOR PRESSURE:- 18.3 mmHg at 680 F
VAPOR DENSITY: 6.7 (AIR=1)
PERCENTVOLAnLE: 100% ~
SOLUBILITY IN WA1ER: 0.16 grams/10a ml @ Tr F
IV. FIRE AND EXPLOSION HAZARD DATA
SPECIAC GRAVITY:
ODOR:........
APPEAAANcE:
1.65
Strong, Irritating.
Cloar, oolorl919s liquid.
FLASH POIN~ None FLAMMABLE LIMITS: Not Flammable
EXTINGUISHING MEDIA: Water fog for cooling of fire exposed contaIners. All conventional fire extInguIshIng'
media are suitable.
SPECIAL FIRE FIGHllNG PROCEDURES: If ohloroplcrln Is stored or spilled In the area of a fire, evacuate area.
Wear self.contalned breathlng.apparatus and full protective clothIng. Cool with water sprayed from a dlstanc'e
upwind. .1
UNUSUAL 'fIRE AND EXPLOSION HAZARD: Not explosIve but heat and ultraviolet light may produce phosgene
and other toxIc compounds. Cylhider may rupture violently In heat of flre. .
v. REACTIVITY DATA
STABILITY: Stable
INCOMPATIBILITY: MagnesIum, aluminum. and their .alloys, and pye pipe or pve containers.
HAZARDOUS OECo"MPOSIllON PRODUCTS: Decomposes at 2340 to chlorlneJ phosg~ne, oarbon monoxide.
and oxides of nItrogen.. -
HAZARDOUS POLYMERIZATION: Will not occur
"
VI. HEALlli HAZARD DATA
GENERAL INFORMATION AND ROUTES OF ENTRY: HIghly toxic liquId and vapor. Noxious odor, acts as own.
warnIng agent against overexposure. Exposure to hazardous levels of chloropicrin cannot be voluntarily.
tolerated. May be fatal If Inhaled or swallowed. Severe damage follows liquId c6ntact with eyes or skIn.
Airborne exposure to concentrations of 0.1 . 0.3 ppm may cause Immediate tearIng and Irritation of the eyes
and Irritation of the respiratory tract or contaminated body surfaces. The FIFRA toxicIty classification Is
Category 1 due to acute lethality and severe Irritation.
PAGE 1 of 2
CHLOROPICRIN CLEARING/WARNING AGENT
VI. HEALTH HAZARD DATA
CARCINOGENICITY: No component presont at greater than 0.01% Is listed by IARC, OSHA, or NTP for
carcinogenicity..
MUTAGENICITY: Has been shown to be positive In somo In vItro ('test tubo') studies and negative In others.
TERATOGENICITY: In animal Inhalation studies thore wore no treatment-rolated fetal malformations although
the Incidences of developmental variations Increased with doso. .
REPRODUCTIVE EFFECTS: Reprod~etive fitness Was not adversely affected In a two-generation Inhalation rat
~~ .
SYMPTOMS OF OVEREXPOSURE: EXposure to vapor oauses tearing and eye, nose, and throat Irritation.
Exoesslve overexposure may result In coughing, nausea, vomlllng, breathing difficulties, or death. LIQuId can
cause severe burns to eyes and akin. Toxlo If Ingested.
HEALTH HAZARDS OR RISKS FROM OVEREXPOSURE: ACUTE - Overexposuro oan be fatal. Irritation of
respiratory tract causes congestion, hemorrhaging, sevoro bronohltls, and edema. CHRONIC _ Unknown.
EMERGENCY FIRST AID PROCEDURES:. .
INHALATION: Get exposed person to fresh air. Keep warm. Make sure person oan breathe freely. If breathing
has stopped, give artificIal resplrallon, preferably mouth-to-mouth. Do not give anything by mouth to any
unconscious person. . . . .
EYES; Hold eyelids open and.f1ush with a steady, gentle stream of water for at least 1S minutes.
SKIN: Immediately remove oontamlnated Clothing, shoes, and other Items covering the skin. Wash
contamInated skin area thoroughly with soap and water.
INGESTION: Ingestion may cause severe gastrointestinal damage and may Include nausea. vomiting, and
abdominal pain, collapse and death.
~
VII. PRECAUTIONS FOR SAFE HANDLING AND USE
SPILL AND LEAK PROCEDURE: Evacuate area. Do not breath vapors. Wear self contained breathing apparatus
(see Seotlon VIII. Respiratory Protection). Move leaking or damaged containers outdoors or to an Isolated
location. Work upwind, If possible.
WASTE DISPOSAL METHODS: Small quantities will evaporate rapidly, or can be absorbed onto vermiculite.
dry sand, earth. or sImilar absorbent material. Such material should be disposed of on site or at an approved
disposal faclllty. .
HANDLING AND STORAGE: Store In a cool, dry, well-ventilated area under Jock and key. Do not contaminate
water, food, or feed by storage or disposal. Store and ship cylinders In upright posIt/on only. Keep valves
closed with bonnets and caps on when not In use, IncludIng when empty.
VIII. CONTROL.MEASURES
RESPIRATORY PROTECTION: Supplied-air respirator (MSHNNIOSH approval number prefix TC-19C) or a
self-contained breathing apparatus (SCBA) (MSHNNIOSH approval number prefix TC-13F). .
VEN11 LATI ON: LOCAL EXHAUST - From point of origin of fumes. GENERAL - Provide exhaust Inside
building.
PROTECTIVE GLOVES: Nitrile or polyethylene gloves are recommended when there is a danger of liquid
contact.
EYE PROTECTION: Full-face shield or safety glasses with brow and temple shields (Do not wear goggles).
. .'
IX. SPECIAL PRECAU110NS
OTHER: Read and observe all precautions on product label prior to use.
PAGE 2 of 2
Revision Date:
06/30/03
RESTRICTED USE PESTICIDE DUE
TO INHALATION TOXICITY
For sale to and use only by Certified Applicators or persons under
their direct supervision and only for those uses covered by the
Certified Applicator's certification.
ZYTHOR
Use to control existing infestations of all life stages of pests such
as drywood termites, beetles (old house borer, powderpost,
deathwatch), bedbugs, clothes moths, German cockroaches and
rodents (rats, mice). Use to control existing infestations of non-egg
life stages only of insects such as dermestid beetles (furniture
carpet, carpet) and cockroaches (oriental, American, brown-
banded), Use to l(ontrol existing infestations of above ground
Formosan termites.
For use in disinfesting structures such as dwellings, buildings,
warehouses, mobile homes. For use in disinfesting vehicles such
as automobiles, buses, recreational vehicles, surface ships,
shipping containers, rail cars, (except aircraft). For use in
disinfesting materials (construction) and furnishings (household
effects).
When using, observe local, state and federal rules and regulations
concerning the use of warning agents, detection devices,
respiratory protection, protective clothing, security requirements
and posting of warning signs,
ACTIVE INGREDIENT
Sulfuryl fluoride...... ... ....... ..... .... .......... ........ .... ....... 99.3%
OTHER INGREDIENTS................................................ 0.7%
TOT AL........... ....... ........ ..... ... .......... ............. ........ .......... 100.0%
KEEP OUT OF REACH OF CHILDREN
~
DANGER ~ POISON
PELIGRO
Si usted no entiende la etiqueta, busque a alguien para que se la
explique a usted en detalle. (If you do not understand the label, find
someone to explain it to you in detail.)
In case of emergency endangering health or the environment
involving ZYTHOR, call 1-800-424-9300, If you wish to obtain
additional product information, visit our website at www.zythor.com
Ensystex II, Inc. Fayetteville, NC 28303 USA
FIRST AID
In all cases of overexposure, when symptoms such as nausea,
difficulty in breathing, abdominal pain, slowing of movements and
speech or numbness in extremities are exhibited, get medical
attention' immediately. Take affected person to a doctor or
emergency treatment facility.
If inhaled: Move person to fresh air. If person is not
breathing, call 911 or an ambulance, then give
artificial respiration, preferably by mouth-to-mouth,
if possible. Call a poison control center or doctor
for further treatment advice.
If liquid is on Immediately apply water to contaminated area of
skin or on clothing before removing. Once area has thawed,
clothing: remove contaminated clothing, shoes and other
items covering skin. Rinse skin immediately with
plenty of water for 15-20 minutes. Call a poison
control center or doctor for treatment advice.
If liquid is in Hold eye open and rinse slowly and gently with
eyes: water for 15-~0 minutes. Remove contact lenses, if
present, after the first 5 minutes, then continue
rinsing eye. Liquid fumigant in the eye may cause
damage due to refrigeration or freeZing. Call a
poison control center or doctor for treatment
advice.
HOT LINE NUMBER
Have the product container or label with you when calling a poison
control center or doctor, or when going for treatment. You may also
call 1-800-424-9300 for emergency medical treatment information.
NOTE TO PHYSICIAN
ZYTHOR is a gas that has no warning properties such as odor, color
or eye irritation. (Chloropicrin, which is used as a warning agent in
conjunction with ZYTHOR, is the active ingredient in tear gas and
will cause tearing.) Early symptoms of exposure to ZYTHOR are
respiratory irritation and central nervous system depression.
Excitation may follow. Slowed movement, reduced awareness and
slow or garbled speech may be noted. Prolonged exposure can
produce lung irritation, pulmonary edema, nausea and abdominal
pain. Repeated exposure to high concentrations can result in
significant lung and kidney damage. Single exposures at high
concentrations have resulted in death. Treat symptomatically.
See inside for Precautionary Statements and Directions for Use
READ THIS ENTIRE LABEL BEFORE USING THIS PRODUCT, ALL
PARTS OF THIS LABEL ARE EQUALLY IMPORTANT FOR SAFE
AND EFFECTIVE USE OF THIS PRODUCT, AS NECESSARY,
CONSULT WITH THE LEAD STATE PESTICIDE REGULATORY
AGENCY TO DETERMINE OR REMAIN INFORMED OF THE
CURRENT REGULATORY STATUS, REQUIREMENTS AND
RESTRICTIONS CONCERNING THE USE OF THIS PRODUCT FOR
FUMIGATION IN THE STATE OF INTENDED USE. CALL ENSYSTEX
II, INC. (PHONE 1-888-398-3772) IF YOU HAVE ANY QUESTIONS OR
DO NOT UNDERSTAND ANY PART OF THIS LABEL.
Notice: Before buying or using this product, read "Terms and Conditions
of Use", 'Warranty Disclaimer", "Inherent Risks of Use" and "Limitation of
Remedies" sections of this label. If terms are unacceptable, return at
once unopened.
EPA Reg, No. 81824-1
EPA Establishment Numbers (Circled letters after Establishment
Numbers below correspond to first letter in Lot # on the container
label.)
68732 - DEU - 002 @
73925 - CHN - 001 @
81805 - CHN - 001 @
NET CONTENTS: As marked on container
Zythor is a registered trademark of Ensystex II, Inc.
PRECAUTIONARY STATEMENTS
Hazard~ to HU"1ans and Domestic Animals
~
DANGER ~ POISON
PELIGRO
Extremely Hazardous Liquid And Vapor Under Pressure. Fatal If
Inhaled . Causes Irreversible Eye Damage . Contact with Liquid
Causes Freeze Burns Of Exposed Skin
Do not get in eyes, on skin or on clothing. ZYTHOR is odorless and
colorless, Exposure to toxic levels may occur without warning or
detection by the user or exposed persons,
Protective Clothing
Wear splash resistant goggles or full face shield for eye protection during
introduction of fumigant or when working around any lines containing fumigant
under pressure. Do not wear gloves or rubber boots. Do not reuse clothing or
shoes that have become contaminated with liquid fumigant until they have been
thoroughly aerated and cleaned.
Respiratory Protection
Use of an approved Respiratory Protection Device (see Respiratory Protection
Devices) is required to enter or remain within a fumigated space anytime the
concentration of ZYTHOR within that space is known to exceed 1 ppm or is
unknown, such as at the start of the aeration process.
If the concentration of ZYTHOR within the fumigated space, as measured by an
approved and properly calibrated Low Fumigant Level Detection Device (see Low
Fumigant Level Detection Devices), does not exceed 1 ppm, no respiratory
protection is required to enter or remain within the fumigated space. Because the
approved detection devices give immediate readings of the levels of fumigant
present, respiratory protection is not required when these devices are in use after
the initial 1 hour aeration procedure is completed. However, whenever a fumigant
level reading exceeding 1 ppm is obtained within a fumigated space, anyone within
the fumigated space not using an approved Respiratory Protection Device must
immediately leave the fumigated space and remain outside the fumigated space
until fumigant level readings of 1 ppm or greater are no longer obtained within the
fumigated space. The concentration of ZYTHOR must be monitored in the
breathing zones. The fumigated space must remain posted until cleared for re-
occupancy.
Respiratory Protection Devices
Use a NIOSH or MSHA approved positive pressure Self-Contained Breathing
Apparatus (SCBA, not SCUBA) or combination air supplied/SCBA respirator, such
as those manufactured by Ranger. Survivair, Scott, or MSA, when respiratory
protection is required (see Respiratory Protection). Required Respiratory
Protection Devices must be on site and operational before an application of
ZYTHOR begins.
Before using any make or brand of Respiratory Protection Device, learn how to use
it correctly. Determine that it is in good working order, that it has an air supply
sufficient (0 supply air for the period of time the device will be in use, that it fits
properly and that it provides an adequate seal around the face.
Low Fumigant Level Detection Devices
As part of the aeration/clearance process or cylinder leak procedure, an approved
Low Fumigant Level Detection Device capable of confirming a concentration of
ZYTHOR of 1 ppm or less, such as the SPECTROS SF-ExplorlR, INTERSCAN or
MIRAN gas analyzers, should be used to sample the air within the breathing zones
of the fumigated space to confirm the level of fumigant, if any, that is still present
The INTERSCAN gas analyzer must be calibrated within one month prior to its use
as a Low Fumigant Level Detection Device. All other approved Low Fumigant
Level Detection Devices must be calibrated according to their manufacturer's
recommendations.
ENVIRONMENTAL HAZARDS
Sulfuryl fluoride is highly toxic to fish and wildlife. Exposure to non-target
organisms should be avoided.
PHYSICAL AND CHEMICAL HAZARDS
Sulfuryl fluoride is a colorless, odorless, non-irritating toxic gas. ZYTHOR cylinders
are under pressure and must not be stored near heat or open flame. Exposure of
the cylinder(s) to temperatures above 1580F will cause a fusible plug in the valve
body to melt and the contents to be released into the atmosphere. Under high heat
conditions (temperatures above 7520F). ZYTHOR can decompose into sulfur
dioxide (S02), hydrofluoric acid (HF) and other decomposition products.
Hydrofluoric acid is highly reactive and can corrode or damage many materials
including metals, glass, ceramic finishes, fabrics, etc.
STORAGE AND DISPOSAL
Do not contaminate water, food or feed by storage or disposal Do not ship or
store with food, feed, drugs or clothing.
Pesticide Storage: Store in a dry, cool, well ventilated area under lock and key.
Post as a pesticide storage area. Store cylinders upright, secured to a rack or
wall to prevent tipping. Storage of ZYTHOR in occupied buildings and spaces is
prohibited unless storage area(s) is equipped with a permanently mounted and
properly maintained and functioning sulfuryl fluoride monitoring device designed
to alert occupants of the building to the presence of sulfuryl fluoride in the air of
the storage area at a level greater than 1 ppm.
Cylinder Return: When cylinder is empty, close valve, screw safety cap onto
valve outlet and replace protection bonnet Follow registrant's instructions for
return of empty or partially empty cylinders. Only the registrant is authorized to
refill cylinders. Do not use cylinders for any other purpose. Always follow the
proper cylinder handling directions.
Pesticide Disposal: Pesticide wastes are acutely hazardous. Improper
disposal of excess pesticide is a violation of Federal law. If the wastes cannot
be disposed of by use according to label instructions, consult your State
Pesticide or Environmental Control Agency or the Hazardous Waste
Representative at the nearest EPA Regional Office for guidance.
DIRECTIONS FOR USE
It is a violation of Federal law to use this product in a manner inconsistent with its
labeling. Carefully read and follow all Directions For Use.
ZYTHOR is a highly hazardous material and should be used only by individuals
trained in its proper use and knowledgeable of its possible hazards. All local. state
and federal rules and regulations regarding security requirements, reentry,
aeration. clearance, posting of warning signs and use of detection devices, warning
agents and respiratory protection equipment must be observed when fumigating
with ZYTHOR
Do not apply this product without first computing the dose to be applied with the
Fumicalc software program. The Fumicalc program, which is available from
Ensystex II, Inc.. is part of the labeling for this product and must be used to
calculate any dose of ZYTHOR
Two persons trained in the use of ZYTHOR, at least one of whom is an applicator
licensed/certified to perform fumigations by the state in which the application is
being performed, must be present on site during any release of ZYTHOR, during
any reentry into the fumigated space within the exposure period and during
initiation of the initial aeration procedure.
If fumigating for insect pests, do not apply ZYTHOR when the lowest temperature
at a site of pest activity within the fumigated space is below 40oF. Generally. the
lowest temperature in a slab structure is found at the slab foundation and the
lowest temperature in a crawl space structure is found just below the surface of the
crawl space soil. No temperature restriction applies when fumigating for rodents.
Remove edible items, including food and feed, from the structure before the
fumigation if they cannot be protected against exposure to ZYTHOR (see
Preparation for Fumigation). Chloropicrin must be used to warn of the presence of
fumigant within the fumigated space (see Warning Agent).
Handling and Transportation of Cylinders
Cylinders should not be subjected to rough handling or mechanical shock such as
dropping, bumping. dragging or sliding. Do not use rope, slings, hooks, tongs or
similar devices to unload or move cylinders. Transport cylinders using a hand truck
or fork truck to which the cylinder can be firmly secured Do not transport any
cylinders in closed vehicles where they occupy the same common airspace as
personnel. Transport cylinders securely and only in an upright position. ZYTHOR
cylinders should never be transported by aircraft under any circumstances.
Do not remove valve protection bonnet and safety cap until immediately before
use. Replace safety cap and valve protection bonnet as soon as practical after
use.
The cylinder valve is designed to retain a small amount of fumigant within the
cylinder when the pressure within the cylinder falls below a certain pressure. This
feature prevents the introduction of unauthorized substances into the cylinder when
it is empty. This is facilitated by a spring loaded residual pressure feature
incorporated into the valve that cuts off gas flow when the pressure of the
remaining gas falls below a certain low level. Do not attempt to defeat this
mechanism as serious injury could result
Cylinder Leak Procedure
Evacuate immediate area of leak. Use an approved Respiratory Protection Device
(see Respiratory Protection Devices) for entry into affected areas to correct the
problem. Move leaking or damaged cylinder outdoors or to an isolated location,
observing strict safety precautions. Work upwind from the cylinder if possible.
Entry into the affected area by persons not using approved Respiratory Protection
Devices is not permitted until the concentration of ZYTHOR in the air of the
affected area is determined to be 1 ppm or less, as determined by an approved
Low Furnigant Level Detection Device (see Low Level Fumigant Detection
Devices).
Compressed Gas Hazards
The release of fumigant under high pressure can be forceful, creating a potential
for personal injury.
A fog-out can occur if ZYTHOR is released too rapidly The chances of this
condition occurring may be decreased by following the instructions contained in this
label (see ZYTHOR Release Preparation).
The rapid discharge of ZYTHOR through introduction equipment will result in the
2 cooling of parts of the equipment and the cylinders. Contact with the cooled
equipment can cause frostbite.
PREPARATION FOR FUMIGATION
Structure Occupant Fact Sheet
Prior to the application of ZYTHOR to a structure, the ZYTHOR Fact Sheet must be
provided to an ~dult occupant of the structure to be fumigated. In the case of a
multi-unit or connected structure (see below), the ZYTHOR fact sheet must be
provided to an adult occupant of each currently occupied individual living unit within
these structures
Fumigating Part(s) of A Structure
When fumigating a single uniVroom that is a part of or within a larger structure
(such as one or more units of a town house, apartment or condominium
building/complex) the space within all units of the entire structure must be
considered to be lumigated space with respect to all requirements concerning
structure entrance security, posting, evacuation. reentry. aeration and clearance.
Fumigating Connected Structures
A connected structure or area is defined as any structure or area connected to or
having in common with the space to be fumigated any construction elements (e.g.
pipes. conduits, ducts, cavities, voids, etc.) which could possibly allow the passage
of fumigant out of the fumigated space into Ihe connected structure(s) or area(s).
When fumigating a space to which other structures or areas are connected, the
connected structure(s) or area(s) must be considered to be a fumigated space with
respect to all requirements concerning structure entrance security, posting,
evacuation, reentry, aeration and clearance.
What to Remove from the Fumigated Space
Remove all persons, non-target animals and desirable growing plants from the
space to be fumigated. Remove mattresses (except waterbeds) and pillows
completely enveloped in waterproof covers or allernately remove covers.
Food, feed, drugs (including tobacco products) and medicines (including those
items in refrigerators and freezers) can remain within the fumigated space if they
are contained within plastic. glass or metal containers with the original
manufacturer's air-tight seal intact.
Protective Bagging of Open Food, Feed and Drugs
. Food, feed. drugs (including tobacco products) and medicines (including those
items in refrigerators and freezers) not in plastic, glass or metal containers with the
original manufacturer's air-tight seal intact must be removed from the fumigated
space or protected against exposure to ZYTHOR if they are left within the
fumigated space.
Items can be protected against exposure to ZYTHOR by double bagging th!,!m in
Fumiguard bags. Fumiguard bags, which are available from Ensystex II, are made
of a material highly resistant to permeation from gases such as sulfuryl fluoride.
Double bag in Fumiguard bags all items that must be protected against exposure to
ZYTHOR that will be left within the fumigated space Double bagging is performed
by placing an item in a Fumiguard bag, twisting the top of the bag closed tightly and
then securing the twisted part of the bag in its closed position. The closed bag is
then double bagged by placing the closed bag inside another bag which is secured
closed in the same manner as the inner bag.
Extinguishing Flames and Disconnecting Heat Sources
Extinguish all flames, including pilot lights of furnaces, water heaters, dryers, gas
refrigerators, gas logs, ranges, ovens, broilers, open flames, etc. Turn off or
unplug all electrical heating elements such as those in heaters. dryers, pianos,
organs, etc. Shut off automatic switch controls for appliances and lighting systems
that will be contained within the fumigated space. Contact your local gas company
to determine what procedures should be followed in your area for shutting off
natural gas or propane service. Gas service should be shut off at the main service
valve. Sulfuryl fluoride can react with strong bases such as some photo developing
solutions
Doors and Openings to Closed Spaces
Open and leave open all operable internal doors. Open and leave open all
operable openings to rooms, attics, sub-areas, storage rooms and closets. Open
and leave open operable doors. covers or lids of any space within which fumigant
could accumulate and linger during aeration including storage cabinets. drawers,
storage chests and appliances (such as washers, dishwashers, dryers. microwave
ovens. conventional ovens, refrigerators, freezers. etc.).
Appliances
Turn off and/or disconnect appliances as appropriate to the circumstances
Alternately leave relrigerators and freezers operating and their doors closed if the
choice is made to leave properly sealed items inside of them. If the choice is made
to leave sealed items in closed refrigerators and freezers during the exposure
period, the appliance's doors should be opened and left open during aeration and
clearance of the fumigated space until the concentration of ZYTHOR within their
interior is 1 ppm or less as measured by an approved and properly calibrated Low
Fumigant Level Detection Device
Air Circulation
Based on the circumstances, it may be necessary to actively circulate the air in all
or part of the fumigated space with properly positioned fans after the release of
ZYTHOA to assure its rapid dispersion within all of the fumigated space Parts of
the structure that may warrant consideration for active air circulation may include
basements, dead air spaces and areas located long distances from a point of
ZYTHOR introduction into the fumigated space If possible, position and aim fans
in such a manner that air closer to the point(s) of ZYTHOR release is circulated
towards points farther Irom the point(s) of ZYTHOR release
Fumigant Confinement
The methods and materials used to confine the fumigant to a space to be
fumigated can vary depending on the nature 01 the space (eg, structure, vehicle.
chamber. vessel) and the inherent resistance of the surtaces that lorm the space to
the movement of the fumigant out of it (e.g.. masonry walls vs wood walls) The
more gas tight the fumigated space inherenfly is or can be rendered to be, the
higher the level of fumigant confinement that can be attained. Consider a
monitored application of ZYTHOR (see Monitored Vs. Un-Monifored Application) to
any fumigated space where there is uncertainty as to whether or not an adequate
level of ZYTHOR can be confined to that space for the intended duration of the
exposure period.
Structure Fumigation Using A Tarpaulin
When and to the extent needed, use tarpaulin(s) made of a material that eflectively
confines and is sufficiently impermeable to the passage of the fumigant through it
such as vinyl coated nylon or polyethylene sheeting of at least 4 mil thickness to
cover the structure or portion of the structure containing the space to be fumigated.
Seal all seams between adjacent tarpaulins. Seal all edges of the tarpaulin that
touch the ground or ground level surface to that surface with, for example, soil,
sand or weighted snakes resting on the edge of the tarp. After tarping, make sure
that all operable windows and interior doors of the fumigated space are open.
Fumigant can be lost (and damage to plants outside the fumigated space around
the exterior of a fumigated structure can occur) when it is able to penetrate the soil
surface within the fumigated space adjacent to where the tarpaulins rest against
the ground and move outward. This movement is retarded when the soil between
the foundation of the structure and the outermost edge of the tarpaulin around the
perimeter of the structure contains a high level of moisture. If soil around the
foundation of the structure is not sufficiently moist to act as a barrier to fumigant
movement, wet all soil between the foundation of the structure and the outermost
edge of the tarpaulin around the perimeter of the structure and around the root
zone of plants that may be potentially affected.
Structure Fumigation Without Using a Tarpaulin
For fumigated spaces or structures that can be adequately sealed against the
excess movement of fumigant out of them without the use of a tarpaulin, seal
adequately around exterior doors, windows, vents, fireplaces and other openings of
the fumigated space. Use sealing materials and techniques proven to adequately
retard the movement of fumigant out of a fumigated space such as tape and
polyethylene sheeting. To minimize escape of fumigant through the soil and to
avoid injury to nearby plants, wet soil (if not sufficiently moist) around the structure
to act as a barrier to fumigant movement.
Chamber Fumigation
Fumigations with ZYTHOR may be conducted in permanent fumigation chambers
enclosed within, or connected to, a larger structure. A permanent chamber is
defined as a durable hard-walled structure engineered specifically for fumigation
that effectively confines ZYTHOA. Monitor indoor areas around the permanent
fumigation chamber for ZYTHOR concentrations with an approved and properly
calibrated Low Fumigant Level Detection Device during the fumigation, especially
during fumigant introduction. No one is permitted in areas where the concentration
of fumigant in the air is greater than 1 ppm unless they are using an approved
Respiratory Protection Device. Aerate ZYTHOR from the chamber by venting it
directly to the outside of the structure using a ventilation system that does not
release ZYTHOR into the structure within whiCh the chamber is located.
Fumigation of Construction Materials, Furnishings (Household
effects) and Vehicles
Preparations should be as appropriate to the particular circumstances. Create a
sufficiently gas tight seal that will adequately confine the fumigant to the fumigated
space for the planned exposure period based on the directions for tarpaulin. non.
tarpaulin and chamber fumigation above. If the sealed fumigant space is created
within a larger structure (e.g., vehicle fumigated within a garage), the space within
the entire structure should be considered fumigated space with respect to all
requirements concerning preparation for fumigant introduction (except fumigant
confinement and warning agent), structure entrance security. posting, evacuation.
reentry. aeration and clearance. Stationary vehicles should be prepared and
sealed following the instructions above. Vehicles, trucks, trailers, shipping
containers, etc. may be fumigated with ZYTHOR, however all aeration/clearance
procedures must be completed before these are transported or driven over public
roads
Fumigation of Surface Ships in Port
Surtace ships in size up to and including large ocean-going ships may be
fumigated with ZYTHOR to control the pests listed on this label. The applicator and
the ship's captain (or owner) shall follow all applicable regulations including those
contained in the Code of Federal Regulations, Title 46 - Shipping, Chapter 1 _
Coast Guard, Part 147A. Except for those persons involved in the fumigation, no
people, plants. or pets may be on-board during fumigation.
The person responsible for the fumigation must notify the master of the vessel, or
his representative. of the requirements relating to the use of Respiratory Protection
Devices and Low Fumigant Level Detection Devices. Emergency procedures,
cargo ventilation, periodic monitoring, inspections and first aid measures must be
discussed with and understood by the master of the vessel or his representative.
If leakage of the fumigant is detected, the person in charge of the fumigation shall
take action to correct the leakage, or shall inform the master of the vessel, or his
representative. when appropriate. of the leakage in order that corrective action can
be taken by them.
Edible commodities, including food and feed. shall not be exposed to the fumigant.
If they are not removed from the vessel they shall be protected from exposure to
the fumigant. The vessel must not be moved during the period of time between
initial fumigant application and final clearance
Approved Respiratory Protection Devices must be worn during reentry into the
fumigated space when reentry occurs between the time of initial fumigant
application and final clearance and a concentration of more than 1 ppm of fumigant
is detected in a breathing zone of the fumigated space during that period.
3
Warning Ag~nt
Chloropicrin is a warning agent that must be released within the space to be
fumigated prior to introduction of lYTHOR into that space. Even at very low levels
of concentration in the air, unprotected exposure to chloropicrin in the air causes
tearing' and smarting of the eyes accompanied by a disagreeable, penetrating
smell. Chloropicrin must be released into the fumigated space only by a Certified
Applicator or someone under their direct supervision. Applicators must observe the
precautionary statements and safety recommendations appearing on the label of
the chloropicrin containing product.
Chloropicrin must be released within a fumigated space at least 5 minutes prior to
introduction of the fumigant. Apply/release 1 fluid oz of chloropicrin per 10,000 to
15,000 cubic feet- (30 ml of chloropicrin per 283 to 425 cubic meters) of fumigated
space. Establish at least one chloropicrin introduction site for each 45,000 cubic
feet (1275 cubic meters) of fumigated space. Dispense no more than 3 fluid ounces
(90 ml) of chloropicrin into a single evaporation container.
Distribution of chloropicrin throughout a fumigated space is enhanced by
applying/releasing it as follows:
1. Place a shallow, wide container directly behind a fan in its air stream.
2. Place a handful of wicking agent, (e.g., cotton) in the bottom of the container.
3. Pour the chloropicrin over the wicking agent.
Do not place chloropicrin into a container made of magnesium, aluminum, or their
alloys, as chloropicrin may severely corrode these metals. Removal of all
chloropicrin evaporation containers from the fumigated space as soon as possible
aller commencement of the initial aeration procedure will speed dissipation of the
chloropicrin from the fumigated space.
The use of chloropicrin is not required when fumigating railcars and shipping
containers; however if chloropicrin is not used, a thorough pre-fumigation walk-
through inspection must be performed of each railcar or shipping container with
their doors being immediately locked upon leaving each car or container. A guard
must be continuously posted during the period between ZYTHOR introduction and
final clearance if no chloropicrin is used.
Securing Fumigated Structure Entrances
During the Exposure Period and Step 2 of the aeration procedures, fumigated
structure(s) must be secured against the possibility of entry into the structure(s) by
anyone other than a Certified Applicator or persons under their direct supervision.
Two levels of security against unauthorized entry must be employed at each
exterior entrance during those periods, if practicable. In addition to the use of
existing locking mechanisms, if present, a secondary locking device must all;o be
used. Secondary locks shall consist of a device or barricade that has been
demonstrated to be effective in preventing the opening of exterior doors or
entrances using normal opening or entering processes by anyone other than the
Certified Applicator or someone under their direct supervision. Consult state and
local regulations for any supplementary instructions and/or restrictions on securing
against unauthorized entry into fumigated structures.
Posting of Fumigated Spaces
All entrances and all sides of the fumigated space including those within structures,
chambers, vehicles, ships and stacks must be posted and placarded with warning
signs. Signs must remain legible during the entire posting period. Post warning
signs in advance of the fumigation in order to keep unauthorized persons away. All
signs must bear the following in English and Spanish:
1. The signal word "DANGERlPELlGRO" and the SKULL and CROSSBONES
symbol in red.
2. The statement, "Area under fumigation, DO NOT ENTERlNO ENTRE".
3. The date of the fumigation.
4. Name and EPA Registration Number of the fumigant.
5. Name, address, and telephone number of the fumigation company and the
licensed/certified applicator.
Signs must remain in place until the fumigated space has been cleared for re-
occupancy according to the applicable aeration procedure.
DETERMINING DOSES AND EXPOSURE PERIODS FOR
ZYTHOR
The amount of ZYTHOR applied to the fumigated space is referred to as the dose.
The level of fumigant present in the air is referred to as the concentration. Dose is
expressed in pounds of fumigant and concentration is expressed in ounces of
ZYTHOR per thousand cubic feet of fumigated space. Achieving target pest
mortality with ZYTHOR is dependent upon the concentration of ZYTHOR present in
the air the target pest is breathing. However, it is also dependent upon the length
of the period of time the target pest is exposed to that concentration (exposure
periOd) and the temperature. For a given temperature and rate of ZYTHOR loss
from the fumigant space, increases in the concentration of ZYTHOR can reduce
the length of the exposure period required to kill a pest. Conversely, under the
same temperature and rate of fumigant loss conditions, increases in the length of
the exposure period can reduce the concentration of ZYTHOR required to kill the
same pest. Concentration in ounces per thousand cubic feet multiplied by the
number of hours in the exposure periOd is referred to as the Kill Power Index.
The Fumicalc computer program, designed to run on most types of desktop and
laptop computers and many handheld computers, is used to calculate the Kill
Power Index that must be achieved within a fumigant space to kill the target pest
and the dose and exposure period necessary to achieve that Kill Power Index. The
Fumicalc program is part of the ZYTHOR labeling and must be used to calculate all
doses and exposure periods for ZYTHOR The Fumicalc accepts as inputs the
factors necessary to compute these values for all labeled target pests The
Fumicalc program is available from Ensystex II, Inc.
Certain insects are more susceptible to exposure to ZYTHOR than others This
means higher Kill Power Indexes must be achieved for certain Target Pests
compared to that needed to kill others. Higher Kill Power Indexes can be achieved
for any fumigated space by administering a higher Concentration of ZYTHOR
and/or extending the Exposure Period, all of which is handled by the Fumicalc
automatically. All you have to do is tell the Fumicalc the Target Pest and it makes
any necessary adjustments to the Kill Power Index.
The egg stage of some Target Pests are not susceptible to sulfuryl fluoride and
thus cannot be killed by ZYTHOR. In this case it may be advisable to fumigate
once at a concentration sufficient 10 control the post-embryonic (larva, pupa, adult)
stages. After any surviving insect eggs have hatched, but prior to these insects'
maturation and deposition of new eggs, fumigate a second time, again at the post-
embryonic life stage concentration.
The Kill Power Index necessary to control different target pests is expressed in the
following.table as multiples of the Kill Power Index required to kill Drywood termites
(Index = 1), assuming the applications occurred under the same conditions. When
the egg stage of a Target Pest cannot be killed with ZYTHOR, the multiple of the
Drywood Termite Kill Power Index that must be achieved to kill the non-egg stages
only is given instead. These multiples apply to the use of ZYTHOR within all types
of fumigated spaces.
Kill Power Indexes for Different Pests (Drywood Termite Index = 1)
Pests Multiple of the Comments
Drywood Termite Kill
Power Index
Rodents 1/2x
Carpet Beelles lx Eggs are not killed
Cockroaches 1x Eggs are not killed
(except German)
Cockroach (German) 1x
Furniture Carpet Beelles 3x Eggs are not killed
Bedbugs 3x
Old House Borers 4x
Formosan Termites 4x Above ground
termites only are
killed. Use in
combination with
other methods to kill
infestations
originating below
ground.
Clothes Moths 6x
Powder Post Beetles and lOx
Death Watch Beelles
MONITORED VS. UNMONITORED APPLICATION
Monitor or monitoring refers to the periodic measurement of the actual
concentration of ZYTHOR contained within the air of the fumigated space.
Monitoring confirms the concentration of ZYTHOR to which the Target Pest is
exposed and allows for correction of variations of the actual from the expected
concentration of ZYTHOR. if necessary. Monitoring can increase the accuracy with
which the needed Kill Power Index is applied and is particularly recommended
when a high level of precision is necessary. A monitored or unmonitored
application of ZYTHOR can be made to any fumigated space for the control of any
type of Target Pest. The ZYTHOR Fumicalc calculator is designed to calculate the
dose of ZYTHOR (and supplements to the dose during the course of the fumigation
in the case of a monitored application, if needed) for any fumigated space for both
monitored and unmonitored applications.
ZYTHOR RELEASE PREPARATION
Prepare to release the ZYTHOR through a shooting tube to be attached to the
ZYTHOR cylinder whose discharge end is positioned within the fumigated space.
The system for introduction of ZYTHOR into the fumigated space (tubing,
connectors, etc.) should be free of leaks and designed to withstand a minimum
burst pressure of 500 pounds per square inch (psi).
If monitoring will occur, run gas sampling lines from representative locations within
the fumigated space to exterior monitoring points before ZYTHOR introduction
Preventing Fogouts
ZYTHOR is packaged as a liquid under pressure. When it is released into the
fumigated space it must be converted into a gas to be effective as a fumigant. This
process of release and conversion, if not properly prepared for and controlled, can
result in damage to surfaces within the fumigated space from contact with water
condensed from the air as the liquid to gas conversion process cools the air into
which the fumigant is introduced and nearby surfaces. Damage can also occur
when unconverted liquid fumigant. possibly present in the fumigated space after it
is released but before it converts to a gas, comes into contact with surfaces that
might be damaged by its presence.
The conversion of ZYTHOR from a liquid in the cylinder to a gas requires a source
of heat. The heat to make this conversion is taken from the air into which the
4 ZYTHOR is released as it contacts the air The need for heat to make this
conversion.can cause problems when the release of fumigant removes enough
heat from the air to cause the air temperature to drop below its Dew Point
temperature The amount 01 moisture a parcel of air can hold is dependent upon
its temperaturE:.. The De", Point temperature for a parcel of air is the lemperature
at which Illat air is holding as much moisture as it can hold If the temperature of
air la11s below its Dew Point temperature, fog can form and moisture can condense
from the air onto nearby surfaces if the temperature 01 these surfaces is low
enough. The higher the percent relative humidity and the lower the temperature of
surfaces in the fumigated space before Ihe introduction of fumigant, the greater the
chance fog will form in the air and/or condensation will form on surfaces.
Condensation can damage surfaces it forms on if they are sensitive to the
presence of moisture.
The conversion of the fumigant from liquid to gas normally occurs almost
instantaneously when it is released into the fumigated space, however it is possible
that, based on the circumstances, some fumigant will remain in its liquid form for a
short period of time after it has been released. This can be a problem if this super-
cooled liquid fumigant is deposited onto surfaces that can be damaged by its
presence, however brief.
Care must be taken to reduce the chances that moisture is condensed from the air
within the fumigated space during fumigant application or that unconverted liquid
fumigant is present within the fumigant space long enough to come to rest on
surfaces. One way to accomplish both of these is to maximize the amount of air
into whichlhe fumigant is released. The greater the number of 'units' of air used to
vaporize each 'unit' of fumigant, the less heat that must be removed from each
'unit" of .tir during the conversion process. This reduces the possibility that the
capacity of tfle air into which the fumigant is released to hold water or fumigant will
be ellCeeded. Increase the volume of air into which the fumigant is released, and
thereby maximize the rate of fumigant vaporization from liquid to gas, by situating
the discharge end of the fumigant shooting tube on the positive pressure side of an
operating fan (blast side) located within a large open area of the fumigated space.
The air movement capacity at the fan should be at least 1,000 cubic feet per minute
for each pound of ZYTHOR released per minute.
Using a small inside diameter shooting tube (1/8 inch) can also reduce the chances
of un-vaporized fumigant coming to rest on surfaces within the fumigated space.
To further protect against the effects of un-vaporized fumigant on surfaces, it is
recommended that protective sheeting, such as polyethylene plastic, be placed on
the ffoors in the vicinity of any fumigant release point. In order to prevent
damage, do not apply fumigant directly to any surface.
Special care should be taken when the percent relative humidity of the air within
the fumigated space is high (the amount of moisture in the air is high compared to
the total amount it can hold). If necessary delay the fumigation until conditions are
more favorable such as when the relative humidity within the structure to be
fumigated is lower.
ZYTHOR RELEASE
Before introducing the fumigant, verify that all required safety equipment is
available and in good working order. Position the ZYTHOR cylinder(s) outside the
space to be fumigated. 00 not connect cylinders to introduction equipment until all
fumigation warning signs have been posted and the space to be fumigated is clear
of persons, non-target animals and is properfy secured.
Release the ZYTHOR from outside the fumigated space Wear splash resistant
goggles or full face shield for eye protection during inlroduction of fumigant or when
working around any lines containing fumigant under pressure. Do not wear gloves
or rubber boots.
AERATION AND CLEARANCE
Aer1ltlon
The final step in using ZYTHOR is to remove it from within the fumigated space
(aeration) an<! to confirm its absence from the fumigated space after the completion
of the aeration process (clearance). Aeration of ZYTHOR from a fumigated space
involves actively exhausting and/or allowing the ZYTHOR to dissipate from the
fumigated'. space out into the atmosphere. Clearance involves sampling the air
willlin the fumigated space with an approved and property calibrated Low Fumigant
Level Detection Device untit readings given by the detection device indicate that
fumigant is ria longer present above 1 ppm within the breathing zones of any room
of the fumigated space. Only when certain periods of lime (see Aeration
Procedures below) have elapsed after the initiation 01 the aeration process and the
Ievet of fumigant remaining is confirmed at the end of tl10se time periods to no
longer exceed 1 ppm can final clearance for re-occupancy be given.
Respiratory Protection Requirements During Aeration and
Clearance
The processes of aeration and clearance of the fumigated space require entry into
the fumigated space while the level of ZYTHOR in the air within the fumigated
space still exceeds 1 ppm All persons entering and/or remaining inside the
fumigated space between the time of initial application 01 ZYTHOR to the fumigated
space and final clearance of the fumigated space must adhere to the requirements
of the Respiratory Protection, Respiratory Protection Devices and Low Fumigant
Levet Detection Devices sections 01 this label.
Aeration Procedures
There are two approved procedures for aeration The aeration procedure used lor a
lumlgated space is based on tile total amount of ZYTHOR per tllousand cubic feet
that was released within the fumigated space during the exposure period. All
structures into which a total 01 more tllan 16 ounces 01 ZYTHOR per thousand
cubic leet ollumlgated space has been released during the Exposure Period must
be aerated using Aeration Procedure 2. All other lumig3ted spaces can be aerated
using either Aeration Procedure 1 or Aeration Procedure 2
Aeration Procedure 1 - Applied Dose 16 oz/1000 cubic feet or less
These steps must be completed in sequence.
Step (1): Aerate the fumigated space with all operable windows and doors open,
aided by the use of 1 or more fans, for a minimum of 1 hour. All of the fans used
shall, in total, be capable of displacing at least 5,000 cubic feet of air per minute.
The fans may be turned off for the remainder of the aeration period if desired.
Step (2): Secure fumigated space and do not allow reentry for a minimum of 6
110urs from the start of the aeration process (first opening of the seal). During this
time, the fumigated space must remain posted.
Step (3): After the minimum 6 hour waiting period, measure the concentration of
ZYTHOR in the breathing zones of each room of the fumigated space using an
approved and properly calibrated Low Fumigant Level Detection Device. If a
concentration 01 ZYTHOR greater than 1 ppm is detected, ventilate the fumigated
space by opening operable doors and windows for at least 10 minutes. Fumigated
space may be cleared for re-occupancy when the concentration of ZYTHOR as
measured with an approved and properfy calibrated Low Fumigant Level Detection
Device is determined to be 1 ppm or less.
Aeration Procedure 2 - Applied Dose More Than 16 oz/1000 cubic
feet
These steps must be completed in sequence,
Step (1): Aerate the fumigated space with all operabfe windows and doors open,
aided by the use of 1 or more fans, for a minimum of 1 hour. All of the fans used
shall, in total, be capable of displacing at least 5,000 cubic feet of air per minute.
The fans may be turned off for the remainder of the aeration period if desired.
Step (2): Secure the fumigated space and do not allow reentry for a minimum of 8
hours Irom the start of the aeration process (first opening of the seal). During this
time, the fumigated space must remain posted.
Step (3): After the minimum 8 hour waiting period, measure the concentration of
ZYTHOR in the breathing zones of each room of the fumigated space using an
approved and properly calibrated Low Fumigant Level Detection Device. If a
concentration of ZYTHOR greater than 1 ppm is detected, ventilate the fumigated
space by opening operable doors and window for at least 10 minutes. Fumigated
space may be cleared for re-occupancy when the concentration of ZYTHOR as
measured with an approved and properly calibrated Low Fumigant Level Detection
Device is determined to be 1 ppm or less.
Final Clearance and Re-occupancy
Do not reoccupy fumigated space, i.e., structure, ship, vehicle or chamber, or move
fumigated vehicles until aeration is complete and clearance has been given.
Warning signs must remain posted until aeration is completed and final clearance
for re-occupancy is given.
TERMS AND CONDITIONS OF USE
II terms of the following Warranty Disclaimer, Inherent Risks of Use or Limitation of
Remedies are not acceptable, return unopened package at once to the seller for a
full refund of the purchase price paid. Otherwise, use by the buyer or any other
user constitutes acceptance of the terms under Warranty Disclaimer, Inherent
Risks of Use and Limitation of Remedies.
WARRANTY DISCLAIMER
ENSYSTEX II warrants that this product conforms to the chemical description on
the label and that it is reasonably fit for the purposes stated on the label when used
in strict accordance with the directions for use, subject to the inherent risks set forth
below. ENSYSTEX II MAKES NO OTHER EXPRESS OR IMPLIED WARRANTY
OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR
ANY OTHER EXPRESS OR IMPLIED WARRANTY.
INHERENT RISKS OF USE
lt is impossible to eliminate all risks associated with use of this product. Lack of
performance or other unintended consequences may result because 01 lactors
such as use of the product contrary to the label directions or contrary to the dosage
and/or exposure period recommendations 01 the Fumicalc, adverse conditions
(such as unfavorable temperatures, high humidity, unfavorable soil conditions,
excessive rainfall, etc.), abnormal conditions (such as excessive winds, tornadoes,
hurricanes), presence of other materials, the manner of application or other factors,
all of which are beyond the control of ENSYSTEX II or the seller. All such risks
shall be assumed by the Buyer and User.
LIMITATION OF REMEDIES
The exclusive remedy lor losses or damages resulting Irom the use of this product
(including claims based on contract, negligence, strict liability or other legal
theories), shall be limited to, at ENSYSTEX II's election, one of the following:
Refund 01 purchase price paid by the buyer or user for product bought or
replacement of amount of product used.
ENSYSTEX II shall not be liable for losses or damages resulting from handling or
use of this product unless ENSYSTEX II is promptly notified of such loss or
damage in writing In no case shall ENSYSTEX II be liable for consequential or
incidental damages or losses even if ENSYSTEX II knew 01, was advised of, or
sllould have been aware 01 the possibility of such damages.
The terms of the Terms and Conditions of Use, Warranty Disclaimer, Inherent
Risks 01 Use and this Limitation 01 Remedies cannot be varied by any written or
verbal statements or agreements. No employee or sales agent of ENSYSTEX II or
the seller is authorized to vary or exceed the terms of the Warranty Disclaimer or
this Limitation of Remedies in any manner.
5
Material Safety Data Sheet
ZVTHOR GAS FUMIGANT
Emergency Phone 1-800-424-9300 (Chemtrec)
1. PRODUCT AND COMPANY IDENTIFICATION
Product Name: Zythor
Chemical Name: Sulfuryl fluoride
Company: Ensystex II, Inc.
Address: 2709 Breezewood Ave., Fayetteville, NC 28303
Daytime Phone: 1-800-398-3772
2. COMPOSITION /INFORMATlON ON INGREDIENTS
Sulfuryl fluoride 99.3% CAS# 2699-79-8 EINECS#: 220-281-5
Carbon dioxide 0.5% CAS# 124-38-9
3. HAZARDS IDENTIFICATION
Compressed gas harmful by inhalation, Sulfuryl fluoride has no
warning properties such as odor, color or eye irritation, Exposure to
toxic and even lethal levels may occur without warning or cletection
during a single exposure, Evacuate Immediate area if leak occurs.
Releases hydrogen fluoride upon decomposition by high heat.
4, ARST-AID
In all cases of overexposure, when symptoms such as nausea, difficulty in
breathing, abdominal pain, slowing of movements and speech or numbness
in extremities are exhibited, get medical attention immediately. Take
affected person to a doctor or emergency treatment facility.
Inhalation: Move person to fresh air. If person is not breathing, call 911 or
an ambulance, then give artificial respiration, preferably by mouth-to-mouth,
if possible. Excessive exposure may severely irritate upper respiratory
tract. Consult a physician in all cases.
Eye Contact: Hold eye open and rinse slowly and gently with water for at
least 15-20 minutes. Remove contact lenses, if present, after the first 5
minutes, then continue rinsing eye. liquid fumigant in the eye may cause
damage due to refrigeration or freezing.
Skin Contact: Immediately apply water to contaminated area of clothing
before removing. Once area has thawed, remove contaminated clothing,
shoes and other items covering skin. Rinse skin immediately with plenty of
water for 15-20 minutes.
Note to Physician: Sulfuryl fluoride is a gas that has no waming
properties such as odor, color or eye irritation. (Chloropicrin, (CAS# 76-06-
2) which is used as a waming agent in conjunction with sulfuryl fluoride, is
the active ingredient in tear gas and will cause tearing.) Early symptoms of
exposure to sulfuryl fluoride are respiratory irritation and central nervous
system depression. Excitation may follow. Slowed movement, reduced
awareness and slow or garbled speech may be noted. Such individuals
should rest in bed for at least 24 hours. Prolonged exposure can produce
lung irritation, pulmonary edema, nausea and abdominal pain. Repeated
exposure to high concentrations can result in significant lung and kidney
damage. Single exposures at high concentrations have resulted in death.
Treat symptomatically.
5. FIRE-AGHTlNG MEASURES
Extinguishing Media: This product does not bum. All means of
extinguishing are acceptable. If cylinders are in a fire area, remove them if
possible. Altemately, water can be used to keep them cool to prevent
discharge of product due to the melting of fusible plugs in the cylinder
valves which will occur at temperatures above 1580F. Use of water may
also help to scrub out part of any hydrofluoric acid and sulphur dioxide
which may be formed by decomposition of the product in a fire.
Hazardous C6mbustion Products: At temperatures above 7520F, sulfuryl
fluoride will decompose into hydrogen fluoride and sulfur dioxide.
Fire fighting Equipment: Firefighters should wear protective clothing and
use self-contained breathing apparatus. When fighting fires in atmospheres
containing potentially high concentrations of sulfuryl fluoride, encapsulating
protective suits should be wom due to possible formation of hydrofluoric
acid. Protective suit material should be compatible with exposure to
hydrofluoric acid.
6. ACCIDENTAL RELEASE MEASURES
Personal Precautions: Wear appropriate safety clothing, respiratory
protection devices and eyelface protection (see Section 8). Evacuate
unprotected personnel that are nearby.
Leak Procedure: Evacuate immediate area of leak. Move leaking cylinder
to an isolated location observing strict safety precautions. If safe to do so,
try to stop leak. Work upwind from the cylinder, if possible. Entry into
affected area(s) by persons not using approved respiratory protection
devices is not permitted until the concentration of sulfuryl fluoride in the air
of the affected area(s) is determined to be t ppm or less, as determined by
an approved Low Fumiganl Level Delection Device (such as ExplorlR.
Interscan, or Miran gas analyzer).
7. HANDLING AND STORAGE
Handling: Use good personal hygiene. Follow proper cylinder handling
directions. See Section 8 for control measures.
Storage: Keep out of reach of children. Product should be stored in
compliance with local regulations. Store in a well ventilated, cool, dry area.
Keep away from heat sources.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Ventilation and respiratory protection information given below is applicable
to handling sulfuryl fluoride during production, packaging, transportation
and storage. Applicators should refer to the product Jabel for personal
protection equipment requirements during application.
Exposure Limits: ACGIH TLV is 5 ppm TWA, 10 ppm STEL OSHA PEL
is 5 PPM TW A. Provide general and/or local exhaust ventilation to control
airborne levels below the exposure limits.
Respiratory Protection: Atmospheric levels should be maintained below
the exposure guidelines. When respiratory protection is required or during
emergency conditions, use a NIOSH approved positive pressure self-
contained breathing apparatus or positive pressure airline with auxiliary
self-contained air supply.
HancllSkin Protection: No skin protection should be needed. Skin contact
with the liquid may cause freeze damage if the liquid is confined to the skin.
Do not wear gloves or rubber boots.
Eye/Face Protection: Chemical proof goggles / face shield
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance/Odor: Colorless, odorless
Relative vapor density (air=l): 3.5 at 68 OF (20 OC)
Boiling poinVrange: - 67 OF (-55.4 OC)
Water solubility: Practically insoluble
Vapor pressure: 15.2 atmospheres at @ 68 OF (20 oc)
10, STABILITY AND REACTIVITY
Chemical Stability: Stable under normal storage conditions.
Conditions to Avoid: Avoid heating product to its decomposition
temperature.
Materials to Avoid: Strong bases.
Hazardous Decomposition Products: Hydrogen fluoride and sulfur
dioxide upon heating above decomposition temperature.
Additional Information: Hazardous polymerization will not occur.
11. TOXICOLOGICAL INFORMATION
Acute Toxicity: Inhalation LC50/Rat/991 ppm Oral LD50/RaV100mglkg
Irritation: Reacts with mucous membranes
Chronic Toxicity: Inhalation, after repeated exposure, various species,
Target organ: respiratory system, nervous system, kidney, skeleton, 20
ppm, observed effect
No teratogenic effect
Carcinogenic Designation: None
12, ECOTOXICOLOGICAL INFORMATION
Acute Ecotoxicity: No Data
Chronic Ecotoxicity: No Data
Other effects: Product is known to have herbicide and insecticide
properties
13. DISPOSAL CONSIDERATIONS
Promptly return all empty cylinders to Ensystex II. Follow proper cylinder
handling and waste disposal guidelines (see label).
14. TRANSPORT INFORMATION
DOT Proper Shipping Name: Sulfuryl Fluoride; Technical Shipping Name:
Sulfuryl Fluoride; DOT Hazard Class: 2.3; DOT Label: Poison Gas; DOT
Packing Group: Inhalation Hazard Zone 0 ; DOT 10#: UN2191
15. REGULATORY INFORMATION
The infonnation herein is given in good faith, but no warranty, expressed or
implied, is made. Consult Ensystex II for further infonnation.
TSCA B(b): Yes
SARA Hazard Classifications:
Immediate (Acute) Health Hazard: Yes
Delayed (Chronic) Health Hazard: Yes
Sudden Release of Pressure Hazard: Yes
Reactive Hazard: Upon heating above decomposition temperature
Fire Hazard: No
State Right-To-Know
The following product components are cited on certain state lists as
mentioned. Non-listed components may be shown in the composition
section of the MSDS.
Sulfuryl Fluoride 002699-79-8 NJ3 PAl
OSHA HAZARD COMMUNICATION STANDARD: This product is a
"Hazardous Chemical" as defined by the OSHA Hazard Communication
Standard, 29 CFR 1910.1200.
Revised 08/01/2005
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~ecimen Label
RESTRICTED USE PESTICIDE DUE TO
INHALATION TOXICITY
For sale to and use only by Certified Applicators or persons under
their direct supervision and only for those uses covered by the Certified
Iicator's certification.
_",Dow AgroSciences
--
Vikane$
Specialty Gas Fumigant
*Trademar1< of Dow AgroSciences LLC
For control of: Existing infestations of insects and
related pests such as (or including) drywood termites,
Formosan termites, powder post beetles, death watch
beetles, old house borers, bedbugs, cockroaches,
clothes moths, rodents (rats, mice), and the larvae and
adults of carpet beetles (except egg stage), oriental,
American, and brown-banded cockroaches.
For use in: Dwellings (including mobile homes),
Buildings, Construction Materials, Furnishings
(household effects), and Vehicles including
automobiles, buses, surface ships, rail cars, and
recreational vehicles (but not including aircraft).
When fumigating, observe local, state, and federal rules and
regulations including such things as use of chloropicrin, clearing
devices, positive-pressure self-contained breathing apparatus,
security requirements, and placement of warning signs,
Active Ingredient
sulfuryl fluoride .................................................................. 99.8%
Inert Ingredients........................... .................................. ........... 0.2%
Total .................................................................. ............... ........ 100%
EPA Reg. No. 62719-4
Precautionary Statements
Hazards to Humans and Domestic Animals
Keep Out of Reach of Children
DANGER * POISON
PELIGRO
Precaucion 81 usuario: Si usted no lee ingles, 110 use este producto
hasta que la etiqueta Ie haya sido explicada ampliamente.
Extremely Hazardous Liquid And Vapor Under Pressure. Inhalation
of Vapors May Be Fatal' Liquid May Cause Freeze Burns of
Exposed Skin
Do not get in eyes, on skin, or On clothing. Vikane* gas fumigant is
odorless, Exposure to toxic levels may occur without warning or
detection by the user,
First Aid
In all cases of overexposure, such as nausea, difficulty in breathing,
abdominal pain, slowing of movements and speech, numbness in
extremities, get medical attention immediately. Take person to a doctor
or emergency treatment facility.
If Inhaled: Get exposed person to fresh air. Keep warm and at rest.
Make sure person can breathe freely. If breathing has stopped, give
artificial respiration. Do not put anything in the mouth of an unconscious
person.
If Liquid Is On Skin: Immediately apply water to contaminated area of
clothing before removing. Once area has thawed, remove contaminated
clothing, shoes, and other items covering skin. Wash contaminated skin
area thoroughly or shower. .
If Liquid Is 1n Eyes: Flush with plenty of water for at least 5 minutes.
Get medical attention.
Note to Physician: Vikane is a gas which has no warning properties
such as odor or eye irritation. (However, chloropicrin is used as a
warning agent and is a known lachrymator). Early symptoms of
exposure to Vikane are respiratory irritation and central nervous
system depression. Excitation may follow. Slowed movement, reduced
awareness, and slow or garbled speech may be noted. Prolonged
exposure can produce lung irritation, pulmonary edema, nausea, and
abdominal pain. Repeated exposure to high concentrations can result
in significant lung and kidney damage. Single exposures at high
concentrations have resulted in death. Treat symptomatically.
Uquid Vikane in the eye may cause damage due to refrigeration or
freezing.
Notice: Read the entire label. Use only according to label directions.
Before buying or using this product, read "Warranty Disclaimer"
and "limitation of Remedies" elsewhere on this label.
In case of emergency endangering health or the environment involving
this product, call 1-800-992-5994. If you wish to obtain additional product
information, visit our web site at www.dowagro.com.
Agricultural Chemical: Do not ship or store with food, feeds, drugs or
clothing.
Directions for Use
It is a violation of Federal law to use this product in a manner inconsistent
with its labeling.
Read all Directions for Use carefully before applying.
MATERIAL SAFETY DATA SHEET
.MDow AgroSciences
VIKANE* GAS FUMIGANT
Emergency Phone: 800-992-5994
Cow AgroSciences LLC
Indianapolis, IN 46268
Effective Date: 10/7/03
Product Code: 91503
MSDS: 000506
11. PRODUCT AND COMPANY IDENTIFICATION:
PRODUCT: Vikane* Gas Fumigant
COMPANY IDENTIFICATION:
Dow AgroSciences
9330 Zionsville Road
Indianapolis, IN 46268-1189
12. COMPOSITION/INFORMATION ON INGREDIENTS:
Sulfuryl fluoride CAS# 002699-79-8 99.8%
Impurities Associated with the Active Ingredient 0.2%
This document is prepared pursuant to the OSHA Hazard
Communication Standard (29 CFR 1910.1200). In addition,
other substances not 'Hazardous' per this OSHA Standard
may be listed. Where proprietary ingredient shows, the
identity may be made available as provided in this standard.
13. HAZARDOUS IDENTIFICATIONS:
EMERGENCY OVERVIEW
Hazardous Chemical. Colorless, odorless compressed
gas. Evacuate immediate area if leak occurs. Excessive
vapor concentrations are attainable and a single exposure
may cause death. Toxic to pets, fish, wildlife, and avian.
EMERGENCY PHONE NUMBER: 800-992-5994
POTENTIAL HEALTH EFFECTS: This section includes
possible adverse effects, which could occur if this material is
not handled in the recommended manner.
EYE: Essentially non-irritating to eyes. Liquid may cause
frostbite.
SKIN: Essentially non-irritating to skin. Liquid may cause
frostbite. No adverse effects anticipated by skin absorption.
INGESTION: Moderate toxicity if swallowed. The oral LDso
for rats is 100 mg/kg. Swallowing is unlikely because of the
physical state.
*Trademark of Dow AgroSciences
I INHALATION: Vapor concentrations are attainable which
may be fatal with single exposure. Excessive exposure may
cause severe irritation to upper respiratory tract (nose and
throat) and lungs. The LCso for a 4-hour exposure for rats is
991-1122 ppm.
SYSTEMIC (OTHER TARGET ORGAN) EFFECTS: In
animals, effects have been reported on the following organs:
I brain, central nervous system, kidney, lung, respiratory tract
and thyroid gland. Observations in animals include
convulsions and tremors. May cause fluorosis of teeth and
bones.
CANCER INFORMATION: Did not cause cancer in
laboratory animals.
TERATOLOGY (BIRTH DEFECTS): Birth defects are
unlikely. Exposures having no effect on the mother should
have no effect on the fetus. Did not cause birth defects in
I animals; other effects were seen in the fetus only at doses
which caused toxic effects to the mother.
REPRODUCTIVE EFFECTS: In animal studies, did not
interfere with reproduction.
14. FIRST AID:
EYES: In case of frostbite, immediately flush eyes with
water; remove contact lenses, if present, after the first 5
minutes, then continue flushing eyes for at least 15 minutes.
Obtain medical attention promptly preferably from an
ophthalmologist.
SKIN: If shoes, gloves, or clothing covering skin become
wet with sulfuryl fluoride, immediately apply water to
contaminated clothing before removing. Once area has
thawed, remove contaminated items covering skin. Wash
thoroughly or shower.
INGESTION: If swallowed, induce vomiting immediately as
directed by medical personnel. Never give anything by
mouth to an unconscious person. Seek medical attention.
INHALATION: Remove to fresh air. If not breathing, give
artificial respiration. If breathing is difficult, oxygen should be
administered by qualified personnel. Call a physician or
transport to a medical facility.
1
MATERIAL SAFETY DATA SHEET
.MDow AgroSciences
VIKANE* GAS FUMIGANT
Emergency Phone: 800-992-5994
Dow AgroSciences LLC
Indianapolis, IN 46268
Effective Date: 1017/03
Product Code: 91503
MSDS: 000506
NOTE TO PHYSICIAN: Treatment of exposure should be
directed at the control of symptoms and the clinical condition
of the patient. Sulfuryl fluoride is a gas, which has no
warning properties such as odor or eye irritation (however,
chloropicrin is used as a warning agent and is a known
lachrymator). The prediction of possible human effects is
based in part on observations made on laboratory animals.
It is predicted that persons exposed to sulfuryl fluoride will
show little evidence of intoxication at first, unless the
concentration is very high (>400 ppm). Early symptoms of
exposure to sulfuryl fluoride are respiratory irritation and
central nervous system depression. Excitation may follow.
Slowed movement, reduced awareness, and slow or
garbled speech may be noted. It is essential to keep such
an individual at bed rest for at least 24 hours. Clinical
observations should be directed at the pulmonary, hepatic,
and renal systems. Prolonged exposure can produce lung
irritation, pulmonary edema, nausea, and abdominal pain.
Repeated exposure to high concentrations can result in
significant lung and kidney damage. Convulsions may ensue
with respiratory arrest being the terminal event. Assisted
respiration may be necessary. Clinical observation is
essential. There is no known antidote for over-exposure to
sulfuryl fluoride.
15. FIRE FIGHTING MEASURES:
FLASH POINT: Not applicable
METHOD USED: Not applicable
FLAMMABLE LIMITS
LFL: Not combustible
UFL: Not combustible
EXTINGUISHING MEDIA: Sulfuryl fluoride is not
combustible. However, if cylinders are in a fire area, water
can be used to keep them cool to help prevent discharge of
product caused by melted fusible plugs on the cylinders.
Use of water will also help to scrub out part of any
hydrofluoric acid and sulfur dioxide, which may be formed by
decomposition of the product in a fire.
"Trademark of Dow AgroSciences
FIRE & EXPLOSION HAXARDS: Cylinders exposed to fire
may vent and release toxic gas through melted fusible plugs
on cylinders. Although sulfuryl fluoride is not combustible, in
temperatures exceeding 4000C (7520F), it will degrade to
form hydrogen fluoride and sulfur dioxide.
FIRE-FIGHTING EQUIPMENT: Wear positive-pressure,
self-contained breathing apparatus and full protective
clothing. When fighting fires in atmospheres containing
potentially high concentrations of sulfuryl fluoride,
encapsulating protective suits should be wom due to
possible formation of hydrofluoric acid. Protective suit
material should be compatible with exposure to hydrofluoric
acid.
16. ACCIDENTAL RELEASE MEASURES:
ACTION TO TAKE FOR SPILLS/LEAKS: Evacuate
immediate area if cylinder begins to leak. Use a NIOSH or
MSHA approved positive-pressure, self-contained breathing
apparatus (SCBA) or combination air-supplied/SCBA
respirator, such as manufactured by Ranger, Survivair,
Scott, or MSA, for entry into affected areas to correct
problem. For leaking cylinders occurring near structure
being fumigated, place the cylinder inside the designated
I structure if it can be done safely. If leaking cylinder occurs
elsewhere, move leaking or damaged cylinder outdoors or
to an isolated location, observing strict safety precautions.
Work upwind if possible. Do not permit entry into leakage
area by unprotected persons until concentration of fumigant
is determined to be 5 ppm or less, as determined by a
detection device with sufficient sensitivity such as an
INTERSCAN or MIRAN gas analyzer. For detailed
information on the source and use of air monitoring devices
or respirators, consult Dow AgroSciences at 800-992-5994.
/7. HANDLING AND STORAGE:
PRECAUTIONS TO BE TAKEN IN HANDLING AND
STORAGE: Handling: Keep out of reach of children. Do not
breathe gas. Keep all unnecessary people and pets out of
area containing sulfuryl fluoride gas. Storage: Store in
original container and away from heat and dwellings.
2
MATERIAL SAFETY DATA SHEET
.MDow AgroSciences
VIKANE* GAS FUMIGANT
Emergency Phone: 800-992-5994
Dow AgroSciences LLC
Indianapolis, IN 46268
Effective Date: 1017/03
Product Code: 91503
MSDS: 000506
8. EXPOSURE CONTROLS/PERSONAL PROTECTION:
RESPIRATORY PROTECTION: Atmospheric levels should
be maintained below exposure guideline. When respiratory
protection is required, use a NIOSH approved self-contained
breathing apparatus or positive-pressure airline with T t
auxiliary self-contained air supply. For emergency and other HAZARDOUS POL YMERIZA ION: Not known 0 occur.
conditions where the exposure guideline may be exceeded, /11. TOXICOLOGICAL INFORMATION:
use a NIOSH approved positive-pressure self-contained
breathing apparatus or positive pressure airline with auxiliary MUTAGENICITY: In-vitro and animal genetic toxicity studies
self-contained air supply. In confined or poorly ventilated were negative.
areas, use a NIOSH approved self-contained breathing I
apparatus or positive pressure airline with auxiliary self- 12. ECOLOGICAL INFORMATION:
contained air supply. ENVIRONMENTAL FATE:
These precautions are suggested for conditions where a
potential for exposure exists. Emergency conditions may
require additional precautions.
EXPOSURE GUIDELINE: Sulfuryl fluoride: ACGIH TL V is 5
ppm TWA, 10 ppm STEL. OSHA PEL is 5 ppm TWA.
ENGINEERING CONTROLS: Provide general and/or local
exhaust ventilation to control airborne levels below the
exposure guidelines. Lethal concentrations may exist in
areas with poor ventilation.
RECOMMENDATIONS FOR MANUFACTURING,
COMMERCIAL BLENDING, AND PACKAGING
WORKERS:
SKIN PROTECTION: No special skin protection should be
needed. Skin contact with the liquid may cause freeze
damage if the liquid is confined to the skin; do not wear
gloves or rubber boots.
EYE PROTECTION: Use chemical goggles.
APPLICATORS AND ALL OTHER HANDLERS: Refer to
the product label for personal protective clothing and
equipment.
"Trademark of Dow AgroSciences
19. PHYSICAL AND CHEMICAL PROPERTIES:
BOILING POINT: -670F (-550C)
VAPOR PRESSURE: 15.2 atmospheres @ 200C
VAPOR DENSITY: 4.3 g/L @ 200C
SOLUBILITY IN WATER: Practically insoluble
SPECIFIC GRAVITY: 1.35 @20oC
APPEARANCE: Colorless
ODOR: Odorless compressed gas
110. STABILITY AND REACTIVITY:
STABILITY: (CONDITIONS TO AVOID) Cylinders may leak
or rupture in a fire.
INCOMPATIBILITY: (SPECIFIC MATERIALS TO AVOID)
Strong base.
HAZARDOUS DECOMPOSITION PRODUCTS: Sulfur
dioxide and hydrogen fluoride under fire conditions with
hydrocarbons.
MOVEMENT & PARTITIONING:
Bioconcentration potential is low (BCF <100 or Log Pow <3).
Potential for mobility in soil is very high (Koc between 0 and
50).
Log octanollwater partition coefficient (Log Pow) is
estimated using a structural fragment method to be 0.41.
Soil organic carbonlwater partition coefficient (Koc) is
estimated to be 6.124.
Henry's Law Constant (H) is estimated to be 3.28E-02 atm-
M3/mole.
DEGRADATION & PERSISTENCE:
The hydrolysis half-life is 18 minutes to 3 days.
3
MATERIAL SAFETY DATA SHEET
.MDow AgroSciences
VIKANE* GAS FUMIGANT
Emergency Phone: 800-992-5994
Cow AgroSciences LLC
Indianapolis, IN 46268
Effective Date: 1017/03
Product Code: 91503
MSDS: 000506
ECOTOXICOLOGY: 115. REGULATORY INFORMATION:
Material is highly toxic to aquatic invertebrates on an acute
basis (LCso or EC50 is between 0.1 and 1 mg/L. NOTICE: The information herein is presented in good faith
Acute immobilization ECso in water flea (Daohnia maana) is and believed to be accurate as of the effective date shown
0.62 mg/L. above. However, no warranty, express or implied, is given.
Growth inhibition EC50 in green alga fSe/enastrum Regulatory requirements are subject to change and may
caoricomutum) is 3.05 mg/L. differ from one location to another; it is the buyer's
Growth inhibition EC50 in green alga (Selenastrum responsibility to ensure that its activities comply with federal,
caoricomutum) is 0.83 mg/L. state or provincial, and local laws. The following specific
information is made for the purpose of complying with
/13. DISPOSAL CONSIDERATIONS: I numerous federal, state or provincial, and local laws and
regulations.
DISPOSAL METHOD: Promptly return all empty cylinders to
Dow AgroSciences. Wastes are toxic. Improper disposal of U.S. REGULATIONS
excess waste is a violation of federal law. If these wastes
can not be disposed of by use according to label instruction,
consult your state pesticide or the hazardous waste
representative at the nearest EPA regional office for
guidance.
114. TRANSPORT INFORMATION:
U.S. DEPARTMENT OF TRANSPORTATION (DOT)
INFORMATION:
Do not ship this material by air.
For all other modes of transportation:
SULPHURYL FLUORIDE/2.3/UN/2191/POISON
INHALATION HAZARD/ZONE D
"Trademark of Dow AgroSciences
SARA 313 INFORMATION: This product contains the
following substances subject to the reporting requirements
of Section 313 of Title III of the Superfund Amendments and
Reauthorization Act of 1986 and 40 CFR Part 372:
I CHEMICAL NAME CAS NUMBER CONCENTRATION
Sulfuryl Fluoride
002699-79-8
99.8%
SARA HAZARD CATEGORY: This product has been
reviewed according to the EPA "Hazard Categories"
promulgated under Sections 311 and 312 of the Superfund
Amendment and Reauthorization Act of 1986 (SARA Title
III) and is considered, under applicable definitions, to meet
the following categories:
An immediate health hazard
A delayed health hazard
A sudden release of pressure hazard
A reactive hazard
TOXIC SUBSTANCES CONTROL ACT (TSCA): All
ingredients are on the TSCA inventory or are not required to
be listed on the TSCA inventory.
4
MATERIAL SAFETY DATA SHEET
.TMDow AgroSciences
VIKANE* GAS FUMIGANT
Emergency Phone: 800-992-5994
Cow AgroSciences LLC
Indianapolis, IN 46268
Effective Date: 1017/03
Product Code: 91503
MSDS: 000506
STATE RIGHT-TO-KNOW: The following product
components are cited on certain state lists as mentioned.
Non-listed components may be shown in the composition
section of the MSDS.
CHEMICAL NAME CAS NUMBER
LIST
Sulfuryl Fluoride 002699-79-8
NJ3 PA1
NJ3=New Jersey Workplace Hazardous Substance (present
at> or = to 1.0%).
PA 1 =Pennsylvania Hazardous Substance (present at > or _
to 1.0%).
OSHA HAZARD COMMUNICATION STANDARD: This
product is a "Hazardous Chemical" as defined by the OSHA
Hazard Communication Standard, 29 CFR 1910.1200.
NATIONAL FIRE PROTECTION ASSOCIATION (NFPA)
RATINGS:
Cateaorv RatinQ
Health 3
Flammability 0
Reactivity 1
COMPREHENSIVE ENVIRONMENTAL RESPONSE
COMPENSATION AND LIABILITY ACT (CERCLA, or
SUPERFUND): To the best of our knowledge, this product
contains no chemical subject to reporting under CERCLA.
116. OTHER INFORMATION:
MSDS STATUS: Revised Section: 2, 3, 4, 8,11,12 & 14
Reference: DR-0015-5588
Replaces MSDS dated: 5/22/01
Document Code: D03-069-447
Replaces Document Code: D03-069-446
The Information Herein Is Given In Good Faith, But No
Warranty, Express or Implied, Is Made. Consult Dow
AgroSciences for Further Information.
.Trademark of Dow AgroSciences
5
L~ g'~
N. Hwy, 301 . Dade City, FL
Phone 567-2395
City of Zephyrhills
Building Department
To Whom It May Concern:
. TERMITE CONTROL (including
pre-construction treatment)
. HOUSEHOLD PEST CONTROL
. LAWN AND ORNAMENTAL
PEST CONTROL (also Spanish
Moss Control)
. TENT FUMIGATION
. RODENT CONTROL
· AQUATIC AND TERRESTRIAL
WEED CONTROL
. BIRD MANAGEMENT
October 31, 2007
Terry Ray is authorized to sign for Boltin Pest
Control, Inc. to obtain a permit.
lsb/
Regards,
BOLTIN PEST CONTROL, INC.
:10-6[2 ~ f;tc,,~
Lacy (1 Boltin
Corporate Secretary
A CORD_ CERTIFICATE OF LIABILITY INSURANCE OP 10 C9 DATE (MMlDDIYYYY)
BOLTI-J. 08/J.5/07
PRODUCER THIS CERTIFICATE IS ISSUED AS A MATTER OF INFORMATION
. , . ONLY AND CONFERS NO RIGHTS UPON THE CERTIFICATE
Hockman Lackey Insurance, Inc. HOLDER. THIS CERTIFICATE DOES NOT AMEND, EXTEND OR
3438 Colwell Avenue ALTER THE COVERAGE AFFORDED BY THE POLICIES BELOW.
Tampa FL 336J.4
Phone:8J.3-636-4000 Fax:8J.3-28J.-J.086 INSURERS AFFORDING COVERAGE NAIC#
INSURED INSURER A: American Safety Risk Ret Grc up
INSURER B: Hanover Insurance Company
Boltin Pest Control, Inc. INSURER c: Bridgefield Employers Ins. Co
Boltin Fumigatin, Inc.
J.5534 US Hithwas 30J. INSURER D:
Dade City F 33 23
INSURER E:
COVERAGES
THE POLICIES OF INSURANCE LISTED BELOW HAVE BEEN ISSUED TO THE INSURED NAMED ABOVE FOR THE POLICY PERIOD INDICATED. NOTWITHSTANDING
ANY REQUIREMENT, TERM OR CONDITION OF ANY CONTRACT OR OTHER DOCUMENT WITH RESPECT TO WHICH THIS CERTIFICATE MAYBE ISSUED OR
MAY PERTAIN, THE INSURANCE AFFORDED BY THE POLICIES DESCRIBED HEREIN IS SUBJECT TO ALL THE TERMS, EXCLUSIONS AND CONDITIONS OF SUCH
POLICIES. AGGREGATE LIMITS SHOWN MAY HAVE BEEN REDUCED BY PAID CLAIMS.
~~I,J~iJ~1f~E P~~~..,Y(~J'IRA~ ---- -_.
LTR NSR[ TYPE OF INSURANCE POLICY NUMBER DATE MMlDDIYY LIMITS
GENERAL UABILITY EACH OCCURRENCE $500,000
I-- UAMi\\3l:: ; YE" Kl::N I l::U
A ~ COMMERCIAL GENERAL LIABILITY TPGJ.042830 08/14/07 08/14/08 $J.OO,OOO
:::J CLAIMS MADE [!] OCCUR PREMISES Ea occurence)
MED EXP (Anyone person) $5,000
I--
PERSONAL & ADV INJURY $J.,OOO,OOO
I--
GENERAL AGGREGATE $J.,OOO,OOO
GEN'L AGGREGATE LIMIT APPLIES PER: PRODUCTS-COM~OPAGG $ J., 000,000
n .nPRO- n
POLICY JECT LOC
AUTOMOBILE LIABILITY COMBINED SINGLE LIMIT
- $ J., 000, 000
B X ANY AUTO AZJ7936037 02/0J./07 02/01/08 (Ea accident)
-
ALL OWNED AUTOS BODILY INJURY
- $
SCHEDULED AUTOS (Per person)
-
X HIRED AUTOS BODILY INJURY
- $
X NON-OWNED AUTOS (Per accident)
-
- PROPERTY DAMAGE $
(Per acddent)
GARAGE LIABILITY AUTO ONLY- EA ACCIDENT $
=1 ANY AUTO OTHER THAN EA ACe $
AUTO ONLY: AGG $
EXCESS/UMBRELLA LIABILITY EACH OCCURRENCE $
:::J OCCUR 0 CLAIMS MADE AGGREGATE $
$
R DEDUCTIBLE $
RETENTION $ $
WORKERS COMPENSATION AND X I TORY lIMITl3 I JUltI-
ER
C EMPLOYERS' LIABILITY 0830-3293J. 0J./0J./07 0J./0J./08
ANY PROPRIETOR/PARTNER/EXECUTIVE E.L. EACH ACCIDENT $ J.OO, 000
OFFICERlMEMBER EXCLUDED? E.L. DISEASE - EA EMPLOYEE $ J.OO, 000
If yes, describe under $500,000
SPECIAL PROVISIONS below E.L. DISEASE - POLICY LIMIT
OTHER
DESCRIPTION OF OPERATIONS / LOCATIONS / VEHICLES / EXCLUSIONS ADDED BY ENDORSEMENT I SPECIAL PROVISIONS
i
CERTIFICATE HOLDER
Workers' Compensation
Compliance
J.3J.3 N. Tampa St., Ste 503
Tampa FL 33602-3328
CANCELLATION
DEP ARTM SHOULD ANY OF THE ABOVE DESCRIBED POLICIES BE CANCELLED BEFORE THE EXPIRATION
DATE THEREOF, THE ISSUING INSURER WILL ENDEAVOR TO MAlL ~ DAYS WRITTEN
NOTICE TO THE CERTIFICATE HOLDER NAMED TO THE LEFT, BUT FAILURE TO DO SO SHALL
IMPOSE NO OBLIGATION OR LIABILITY OF ANY KIND UPON THE INSURER, ITS AGENTS OR
REPRESENTATIVES.
AUJ: EP.~E_~~NTATf.EE; .1_
~ ~~'*It" -
ACORD 25 (2001/08)
@ ACORD CORPORATION 1988
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STATE OF FLORIDA
J)tpartmtnt of agriculturt anb €on~umtr &trbtct~
BUREAU OF ENTOMOLOGY & PEST CONTROL
Date
July 10, 2007
FileNo.
JE2895
Expires
July 31,2008
THE ID CARD HOLDER NAMED BELOW HAS REGISTERED UNDER
THE PROVISIONS OF CHAPTER 482 FOR mE PERIOD EXPIRING: July
31,2008 AT
BOL TIN PEST CONTROL INC
DADE CITY, FL 33523
?
HERBERT H BOLTIN JR
BOLTIN PEST CONTROL INC
15534 US 301
DADE CITY, FL 33523
Certified Operator
Certified Operator - Fumigatio <,
~#~
CHARLES H BRONSON, COMMISSIONER
STATE OF FLORIDA
~tpartmtnt of agriculturt anb ~n~umtr ~trbitt~
BUREAU OF ENTOMOLOGY & PEST CONTROL
Date
June 26, 2007
FileNo.
JF1295
Expires
JlIne 1, 2008
THE CERTlFIEI) PEST CONTRQL OPERATO~NAMED BELOW HAS
REGISTERED UNDER THE PROVISIONS OF CHAPTER 482 FOR THE
PERIOD EXPIRING: June 1, 2008
HERBERT H BOLTIN JR
15534 US 301
DADE CITY, FL 33523
Pest &
~#~
CHARLES H BRONSON, COMMISSIONER
Control
& Ornamental
& Other WDO Contr