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<br />. Rl:./ORT M..tlBER: 9'11 LNlVAR lEA II>[:. <br />MsDs NO: .39048 ~TERI~ &'fl.1Y MTA !HEr <br />~I~RAI'f.: UPU}1D DATE: 07/16/04 <br /> <br />PAGE: 002 <br /> <br />I"f-RSI(}.l: 002 <br /> <br />.l.CT: CH..OROPICRIN <br /> <br />DRIER NO: <br />PROD NO : <br /> <br />1.. PROIl.tT AND aJ1Pf.#( lIENTIFlCATICN: <br />PRODUCT: Chloropicrin <br />(;CMPAi\IY HENrIFICATICN: <br />Dow AgroSciences <br />9330 Zionsville Road <br />Indianapolis, IN 46268-1189 <br />2. CCJ1POSITICWII>fDRW-l TICN CN INGREDIENTS: <br />Chloropicrin CAS t 0CIXJ76-06-2 96X <br />Tl'ace quantities of water and tr.l 4% <br />This document is pl'epal'ed pur,,uant to the OSHA Ha1.iwd <br />Communication Standard (29 CFR) 1910,1200), In <br />addition, other substances not IHazardous' per this ~ <br />Standard may be listed. Where proprietary ingredient <br />shows, the identity may be made iN'cl:i.li:lb].e as provided in <br />this standal'd. <br />3. ~.lAROCUS lIENTIFICATIOO: <br />r~y O..EI\\lIEW <br />h,._drdous. Colorless liquid with intenSf-~ly irritating tear <br />gas odor, M~ cause severe ~e irrit.ation with cOI'neal <br />injury Iatlich may result in permanent impairment of vision, <br />even blindnt:'5s, Painful irdtation of the ~es at 1 ppm or <br />less; a concentration of 1~; ppm for longer than 1 minute is <br />intolerable to humans. Single prolonged exposure may <br />rf.:'Slllt in the material bF.!:i,ng absorbed in amounts tJtich <br />could cause death. L[fl,) for skin absorption in l'abbits is 62 <br />lI\g/kg. Oral LD50 for male rats is 2'..iO mg/kg, Single bri(..rf <br />(minutes) inhalation expOSUI'e to easily attainable <br />concentration may cause serious adllerSf.! effects, eyen <br />death. Toxic to fish and aquatic organisn~. DOT <br />Classi-ricahon is CH.OROPICRIN, 6,1, \.JIl1580, I, <br />POISll\l-ItfV:LATICN Hf>lARD, f-~lARD ZQ1\E B. <br />E:.rERGEN.::Y PHJ\E M.R1I:E:R: 8OO-m-5994 <br />POTJ:.'ffIAI... /-[Al.TH EFFECTS: This section includes <br />possible adverse effects tJJich could occur if this material <br />is not handll?d in the rec!l1TllleTldecf manner. <br />EYE: M~j CalL$!? pain. May cause severe eye irritation with <br />corneal injul'Y lJIich may I'esull in permal1ent. i1l1pai,rment of <br />vision, even blindness. Vapors cause lacrimation, and <br />painful il'ritation of the gyes at 1 ppm or less; a <br />concentration of 15 ppm for longer than 1 minute is <br />intolerable to humans because of the inten.,e il'ritahon <br />p!Jlduced . <br />f : Short single exposure may cause severe ~;kin bUI'TIS. <br />A single prolonged exposure may result in the material <br />being absorbed in amounts Mlich could cause death. The <br />L050 for skin absorption in rabbits is 62 mg/kg. Vapors may <br />